Thursday, February 28, 2013

Hydrocarbon

1.a



,

serve: 4-(2,2-dibromoethyl)-3,5-dichloroheptane

b.





make: 6-sec-butyl-3,10-dimethyl-cyclodecyne
c.





rejoinder:cis-3,3-dimethyl-4-propyl-1,5-octadiene or (Z)-3,3-dimethyl-4-propyl-1,5-octadiene

2. Predict the major(ip) organic product for each reaction below.

a.





Answer:




b.





Answer:
c.



Answer:


d.





Answer:


3. In an abandoned laboratory has been be a flammable liquid, A, in a bottle presence only the label Compound A: [pic]. Government agents conduct offered you a considerable sum to determine the structure of this compound. afterwards verifying the molecular formula by elemental analysis, you commence that Compound A reacts with 1 mol equiv of hydrogen; and, after treatment with unpleasantic [pic], Compound A gives the dicarboxylic acid C (see below). Another bottle from the same laboratory is labelled Compound B (isomer of A). Compound B also reacts with 1 mol equiv of hydrogen, but yields cyclohexanone after treatment with acidic [pic].



a. point structures for A and B.

Answer:
b. What was the other product formed in the [pic] oxidation of B?

Answer:[pic]


4. Show all reagents and intermediates necessity to carry out the following conversions.





Answer:



5. The least activated compound in an SN2 reaction.

Answer:

[pic]

6. The best nucleophile in a substitution reaction at a primary carbon.

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Answer:











7. The least reactive compound in a SN1 reaction.

Answer:



8. The best solvent for an SN2 reaction.

Answer:







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